Refrigerant scenario - Rules and regulations

Refrigerant scenario - Rules and regulations

Worldwide agreements

The history of refrigerants started almost 200 years ago. During the XIX century and beginning of the XX, refrigerants available in nature were used. However, security problems due to flammability and toxicity led to the use of CFC and HCFC synthetic refrigerants.

In 1973, it was found that the emissions of Cl-atoms present in CFCs and HCFCs depleted the ozone layer. The problem was first addressed in 1985, when representatives of different states met in Vienna to define the actions to protect the ozone layer.

The concrete actions for the reduction of the production and consumption of ozone depleting substances, like R-12 and R-22, are collected in the Montreal Protocol on Substances that Deplete the Ozone Layer, signed by 197 parties in the world on 16 September 1987 and entered into force on 1 January 1989. The initial agreement was designed to reduce the production and consumption of several types of CFCs and halons to 80 % of 1986 levels by 1994 and 50 % of 1986 levels by 1999. In the subsequent meetings, the last one was in Kigali (2016), the protocol was revised in order to speed up the phasing out of ozone-depleting substances. For example, the Copenhagen amendment included the phase out of CFCs by 1995 and the phase out of HCFCs by 2029 with a gradual phase-down.

In this context, the use of HFCs such as R-404A and R-410A was extended in refrigeration and air conditioning applications. Some years later, however, it was discovered that fluorinated refrigerants such as HFCs negatively affects the greenhouse effect. With the scope of address this new finding, the United Nations Framework Convention on Climate Change (UNFCCC) was celebrated in Rio de Janeiro (1992), that commits State Parties to reduce greenhouse gas emissions.

Within this framework, the Kyoto Protocol was adopted 5 years later (in 1997), entering into force on 26 February 2005. There are currently 192 parties (Canada withdrew effective December 2012) to the Protocol. In effect, the Kyoto Protocol required the world developed countries to reduce greenhouse gas emissions by 5% compared to the year 1990 levels by 2008-2010.

In this scenario, Montreal Protocol Parties were aware of the importance of reducing the greenhouse emissions to the atmosphere. To this end, they met in Kigali in October 2016, where a global agreement was signed by 196 countries that are parties to the Montreal Protocol. The international phase-down of 85 % of HFCs by the late 2040s was agreed, that would help to avoid up to 0.5 degree Celsius of global temperature rise by 2100, while continuing to protect the ozone layer.

First reductions by most developed countries started in 2019. These countries will follow with a reduction of HFCs consumption levels in 2024, whereas first reductions in most developing countries will start from 2029, as shown in the following graph:


Phase-down schedule for HFCs according to Kigali Agreement

Key:

  • EU will follow its own F-gas Regulation phase-down (dotted)
  • A2 refers to the developed countries (EU excluded)
  • A5 Group 1 are countries under development
  • A5 Group 2 are the following countries under development: GCC (Gulf Cooperation Council: Saudi Arabia, Kuwait, Bahrain, Qatar, UAE, Oman), India, Iran, Iraq and Pakistan.

Kigali amendment to Montreal Protocol entered into force in January 2019. Currently, some countries have established the concrete measures to comply with it. In the following, some of them are summarized.

 

Regulations by country

European Union: F-gas  

The F-gas Regulation is part of the EU’s environmental policy aim of protecting the environment by reducing emissions of fluorinated greenhouse gases. The latest revision of the F-gas regulation entered into force in March 2024.

Phase down

The maximum quantity of HFCs available to be allocated as quotas for producers and importers from 2025 to 2050, in percentage terms with respect to the 2015 base-value, is represented in the following graph:


Maximum amount of HFC refrigerants, in percentage with respect to the baseline, allowed to be placed on the EU market in the period 2025-2050

It should be highlighted that the quota is applied only to HFC refrigerants, thus HFOs are not included. A mixture is considered to be an HFC if it contains an HFC refrigerant even if the proportion is small.
It should also be noted that the quota system has been extended to MDIs (metered dose inhalers) from January 2025, which means that a part of the quota will not be available for the RACHP sector.

Bans on placing on the market

The new F-gas regulation introduces new bans on the use of refrigerants for specific applications. One important introduction is that, in some cases, the use of any fluorinated refrigerant will be prohibited. Other bans are based on the extent to which the refrigerant contributes to global warming, in terms of GWP, as in the previous version of the F-gas. All these restrictions impact ACHPs, refrigeration units and chillers. The table below also shows the restrictions on the use of fluorinated refrigerants for these applications:

  2025 2026 2027 2028 2029 2030 2031 2032 2033 2034 2035
Domestic refrigeration   No F-gases*
Fridges/freezers for commercial use (self-contained) <150 GWP
Other self contained ref. equipment <150 GWP*
All other stationary refrigeration equipment <2500 GWP (except equipment T<-50°C) <150 GWP*
 
Chillers (≤12 kW)   <150 GWP* No F-gases*
Self contained ACHP (≤12 kW)   <150 GWP** No F-gases**
Split ACHP (≤12 kW) Air-Water   <150 GWP* No F-gases*
Split ACHP (≤12 kW) Air-Air   <150 GWP* No F-gases*
 
Chillers (>12 kW)   <750 GWP*
Self contained ACHP (12-50 kW)   <150 GWP**
Self contained ACHP (>50 kW)   <150 GWP**
Split ACHP (>12 kW)   <750 GWP* <150 GWP*

Refrigerants that will be allowed in different RACHP applications starting from 2025 according to the new F-gas regulation

*except when required to meet safety requirements
**when safety requirements would not allow using fluorinated greenhouse gases with GWP of 150 or less, the GWP limit is 750

In addition to these bans, a GWP limit of 1000 on fluorinated gases will be set for the export of stationary RACHP equipment. It came into force on 12 March 2025. 

United States: AIM ACT and SNAP Rules 

The use of fluorinated refrigerants in the US is regulated by The American Innovation & Manufacturing Act (AIM Act), signed in December 2020. According to this act, the US Environmental Protection Agency (EPA) has the authority to regulate HFCs in three ways: phasing down production and consumption, facilitating the transition to next-generation technologies through sector-based restrictions, and regulating refrigerant management.

Phase down of HFCs

In line with the Kigali Amendment to the Montreal Protocol, the objective of the AIM Act is to phase out the production and consumption of HFCs in the US by 85% before 2035. As shown in the following graph, the allowance limits have been reduced from 90 to 60% in 2024, the biggest reduction so far. The next step will be in 2029 (30%), followed by further reductions in 2034 (20%) and 2036 (15%).


HFC phase down schedule in the period 2020-2040 according to the AIM Act

Regulatory Actions for Technology Transitions

The final rule “Phasedown of Hydrofluorocarbons: Restrictions on the Use of Certain Hydrofluorocarbons under Subsection (i) of the American Innovation and Manufacturing Act of 2020” was signed on 5 October 2023. This rule restricts the use of high GWP HFCs in new aerosol, foam, and RACHP products and equipment. In most applications, the EPA has set a maximum GWP limit on HFCs or HFC blends that can be used, whereas in a few applications, the EPA has listed the specific HFCs or HFC blends that are restricted. It should be noted that the restrictions affect the sale, distribution, and export of products three years after the manufacture/import restriction dates.

The following table shows the GWP limits and the year of banning for the manufacture, import and installation of ACHPs, refrigeration units and chillers.

End-use GWP limit Year
Stationary residential and light commercial ACHP 700 2025
Residential dehumidifiers 700 2025
Household refrigerators and freezers 150 2025
Retail food refrigeration (stand-alone units) 150 2025
Vending machines 150 2025
Refrigerated transport (T > -50°C) 700 2025
Self-contained automatic commercial ice machines Ice maker products (batch type: harvest rate ≤1000 lb (453.6 kg) ice per 24 hours; continuous type: harvest rate ≤1200 (544.3 kg) lb ice per 24 hours) 150 2026
Retail refrigerated food processing and dispensing products Products outside the scope of UL 621, Ed.7 150 2027
Chillers (stand-alone) Comfort cooling 700 2025
Ice rinks 700 2025
Industrial process refrigeration, T > −30 °C (−22 °F)  700 2026
Industrial process refrigeration, T ≥ −50 °C (−58 °F) and T ≤ −30 °C (−22 °F) 700 2028
Data centers, computer room AC and information technology equipment cooling Data centers, computer room AC and information technology equipment cooling 700 2027
Motor vehicle AC New light-duty passenger vehicles 150 2025
New medium-duty passenger vehicles 150 2028
Nonroad vehicles 150 2028
Cold storage warehouse systems Refrigerant charge capacity ≥ 200 lbs (90.72 kg) 150 2026
Refrigerant charge capacity < 200 lbs (90.72 kg)  300 2026
Cascade refrigerant systems on the high temperature side of the system 300 2026
Industrial process refrigeration (not using chillers) Refrigerant charge capacity ≥ 200 lbs (90.72 kg), T > −30 °C (−22 °F) 150 2026
Refrigerant charge capacity < 200 lbs (90.72 kg), T > −30 °C (−22 °F) 300 2026
The high T side of cascade systems with T > −30 °C (−22 °F) 300 2026
T ≥ −50 °C (−58 °F) and T ≤ −30 °C (−22 °F) 700 2028
Remote condensing units in retail food refrigeration systems Refrigerant charge capacity ≥ 200 lbs (90.72 kg) 150 2026
Refrigerant charge capacity < 200 lbs (90.72 kg) 300 2026
Cascade refrigerant systems  300 2026
Supermarket systems Refrigerant charge capacity ≥ 200 lbs (90.72 kg) 150 2027
Refrigerant charge capacity < 200 lbs (90.72 kg)  300 2027
Cascade refrigerant systems, on the high T side of the system 300 2027

Restricted products in the USA for RACHP according to the GWP values of the refrigerants contained in such products

Note that the interim final rule provides one additional year for the installation of new residential and light commercial ACHP systems when using components that were manufactured or imported before 2025. It should be also highlighted that residential ice makers are not included in the household refrigerator and freezer subsector and are not subject to the restrictions indicated in the previous table.

The following table shows specific HFCs or HFC blends that are restricted by the AIM Act:

End-use   Refrigerant bans Year
Refrigeration transport Road and Marine (Selfcontained products) R–402A, R–402B, R–404A, R–407B, R–408A, R–410B, R–417A, R–421A, R–421B, R–422A, R–422B, R–422C, R–422D, R–424A, R–428A, R–434A, R–438A, R–507A, R–125/290/134a/600a (55/1/42.5/1.5), RS–44 (2003 formulation) or GHG–X5 2025
Automatic commercial ice machines Batch type with harvest rate > 1000 lb ice per 24 hours, and continuous type with harvest rate > 1200 lb ice per 24 hours R–402A, R–402B, R–404A, R–407A, R–407B, R–407C, R–407F, R–408A, R–410A, R–410B, R–411A, R–411B, R–417A, R–417C, R–420A, R–421A, R–421B, R–422A, R–422B, R–422C, R–422D, R–424A, R–426A, R–428A, R–434A, R–437A, R–438A, R–442A, R–507A, HFC–134a, R–125/290/134a/600a (55/1/42.5/1.5), RB–276, RS–24 (2002 formulation), RS–44 (2003 formulation), GHG–X5, G2018C, or Freeze 12 2027
Remote condenser R–402A, R–402B, R–404A, R–407B, R–408A, R–410B, R–417A, R–421A, R–421B, R–422A, R–422B, R–422C, R–422D, R–424A, R–428A, R–434A, R–438A, R–507A, R–125/290/134a/600a (55/1/42.5/1.5), RS–44 (2003 formulation), or GHG–X5 2027
Refrigerated food processing and dispensing products Products outside the scope of UL 621, Ed.7 R–402A, R–402B, R–404A, R–407A, R–407B, R–407C, R–407F, R–407H, R–408A, R–410A, R–410B, R–411A, R–411B, R–417A, R–417C, R–420A, R–421A, R–421B, R–422A, R–422B, R–422C, R–422D, R–424A, R–426A, R–427A, R–428A, R–434A, R–437A, R–438A, R–507A, HFC–134a, HFC–227ea, R–125/290/134a/600a (55/1/42.5/1.5), RB–276, RS–24 (2002 formulation), RS–44 (2003 formulation), GHG–X5, or Freeze 12 2027
Products within the scope of UL 621, Ed.7 R–402A, R–402B, R–404A, R–407A, R–407B, R–407C, R–407F, R–407H, R–408A, R–410A, R–410B, R–411A, R–411B, R–417A, R–417C, R–420A, R–421A, R–421B, R–422A, R–422B, R–422C, R–422D, R–424A, R–426A, R–427A, R–428A, R–434A, R–437A, R–438A, R–507A, HFC–134a, HFC–227ea, R–125/290/134a/600a (55/1/42.5/1.5), RB–276, RS–24 (2002 formulation), RS–44 (2003 formulation), GHG–X5, or Freeze 12 2028
Remote condenser R–402A, R–402B, R–404A, R–407A, R–407B, R–407C, R–407F, R–407H, R–408A, R–410A, R–410B, R–411A, R–411B, R–417A, R–417C, R–420A, R–421A, R–421B, R–422A, R–422B, R–422C, R–422D, R–424A, R–426A, R–427A, R–428A, R–434A, R–437A, R–438A, R–507A, HFC–134a, HFC–227ea, R–125/290/134a/600a (55/1/42.5/1.5), RB–276, RS–24 (2002 formulation), RS–44 (2003 formulation), GHG–X5, or Freeze 12 2027

Refrigerant banned in the USA for refrigeration applications in the next years

Manufacturers must ensure that, in addition to meeting the restrictions set under the AIM Act Technology Transition Rule, they also comply with the EPA’s Significant New Alternatives Policy (SNAP) regulations. The SNAP program reviews substitutes on the basis of the environmental and health risks, including factors such as ODP and GWP, toxicity, flammability, and exposure potential within a comparative risk framework of different industrial sectors, including refrigeration and AC.

Finally, it should be highlighted that there are some states, such as California, New York and Washington that go beyond the SNAP rulings and impose stricter GWP limits in some applications.

Japan: "Act on Rational Use & Proper Management of Fluorocarbons"  

This regulation addresses issues throughout the lifecycle of fluorocarbons. It classifies refrigerants according to their GWP and specifies the date these are banned for each application:

Designated products Present refrigerant Target value (GWP) Target year
Room air-conditioning R-410A, R-32 < 750 2018
Commercial air-conditioning R-410A < 750 2020
Condensing unit and refrigerating unit R-404A, R-410A, R-407C, R-744 (CO2 < 1500 2025
Cold storage warehouse
(for more than 50,000 m3)
R-404A, R-717 (Ammonia) < 100 2019

Other requirements that HVAC/R equipment should comply are enumerated in the following:

  • indications and label to designated products (showing “non-F-gas using” or degree of achievements to the target GWP value, target year and target GWP value, GWP value of the refrigerant used in the products), with the purpose of promoting designated products using low-GWP or natural refrigerant;
  • regular leak checks, call service to arrange repairs before refilling as soon as leakages are found, record maintenance, and disclose to maintenance operators, etc;
  • calculation of the annual F-gas leakage amounts. If that amount exceeds 1,000 tonnes of CO2 equivalent, users, as a company, need to report it to the relevant competent ministries, with information on the offices and factories from which the leakage was detected. The Ministry of the Environment (MOE) and the Ministry of Economy, Trade and Industry (METI) will notify the relevant municipal and prefectural governors on the results and the names of the companies, etc., and will publish them.

China: "First Catalogue of Recommended Substitutes for HCFCs"  

An accelerated phase-out schedule for HCFCs is planned. The steps are: reduction of 10% by 2015, reduction of 35% by 2020, reduction of 67.5% by 2025, reduction of 100% by 2030, allowance of 2.5% of baseline (2013 annual CO2 - eq.) for the period 2030-2040, and complete phase out by 2040. The following table shows the recommended refrigerants that can substitute R-22 for each application according to Chinese authorities:

Alternatives ODP GWP Typical applications Common refrigerants
R-290 0 3 Room AC, domestic HP water heater, commercial self-contained refrigeration system, industrial refrigeration systems R-22
R-600a 0 3 Freestanding refrigeration equipment for commercial use R-22
R-744 0 1 Household HP water heaters, industrial or commercial HP water heaters, industrial or commercial refrigeration equipment, refrigeration equipment for cold storage R-22
R-717 0 0 Industrial refrigeration equipment, refrigeration equipment for cold storage, compression condensing units R-22
R-32 0 675 Unitary AC, chilled water (HP) units, industrial or commercial HP water heaters, multi-connected AC (HP) units R-22
R-1234ze 0 <1 Large and medium-sized chilled water (HP) units R-22
R-1234zd 0 1 Large and medium-sized chilled water (HP) units R-22
R-515B 0 287 Large and medium-sized chilled water (HP) units R-22
R-513A 0 631 Large and medium-sized chilled water (HP) units R-22

Recommended refrigerants in China for typical RACHP applications

Canada: "Regulations Amending the Ozone-depleting Substances and Halocarbon Alternatives Regulations (Proposal)"  

Canada proposal indicates refrigerants that are banned from 2020 onwards for each application according to the value of GWP:

Product Use Date GWP
Stand-alone medium-temperature refrigeration system Commercial / industrial 1 Jan 2020 1400
Domestic appliances 1 Jan 2025 150
Stand-alone low-temperature refrigeration system Commercial / industrial 1 Jan 2020 1500
Domestic appliances 1 Jan 2025 150
Centralized refrigeration system Commercial / industrial 1 Jan 2020 2200
Condensing unit Commercial / industrial 1 Jan 2020 2200
Chiller Commercial / industrial 1 Jan 2025 750
Mobile refrigeration system Commercial / industrial 1 Jan 2025 2200

Regulations Amending the Ozone-depleting Substances and Halocarbon Alternatives Regulations in Canada

Australia: "Ozone Protection and Synthetic Greenhouse Gas Management Amendment Bill 2017"  

Australia’s HFC phase-down started in January 2018. The HFC phase-down in Australia means a gradual reduction in the maximum amount of HFCs permitted to be imported into Australia, as reduced imports lead directly to reduced emissions.

The HFC phase-down is being implemented through the “Ozone Protection and Synthetic Greenhouse Gas Management Act” and associated regulations through a quota system for imports of HFCs as bulk gas.

It should be noted that the HFC phase-down covers only imports of bulk gas such as in cylinders. This means that refrigerants imported in pre-charged equipment such as ACs or refrigerators are not included, because they are accounted for in the country of manufacture. Moreover, existing equipment that has already been imported into Australia is not affected by the phase-down.

As regards specific HFC prohibitions, the import and manufacture of small AC equipment using refrigerant with a GWP over 750 is prohibited in Australia from July 2024, including equipment that is imported without refrigerant. The ban will apply to equipment with up to a 2.6 kg refrigerant charge (per the compliance/rating plate), where it is intended for use in cooling, heating, or both heating and cooling, a stationary space, primarily for human comfort. However, similar AC equipment that is ducted, for mobile applications such as caravans and boats, or to systems for use in electrical enclosures and computer rooms are not included.

 

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